The Glue Book

 

The Glue Book

HOW TO SELECT

PREPARE AND

USE GLUE

A SHORT, PRACTICAL
DISCUSSION OF MATTERS
IMPORTANT TO EVERY
GLUE USER

J. A. Taggart, Toledo, Ohio

1913

modern glue testing

 

THE purpose of this manual is to provide a practical guide for glue users, to help in eliminating waste and improving the quality of product.
That there is an enormous waste due to improper preparation and use of glue is well known to all who are in touch with the subject.
Some authorities estimate that 70% of the glue used in the United States is improperly handled. The actual waste is said to be in excess of 25% of the amount of glue used; to say nothing of the loss due to imperfect condition of the completed work.
The writer knows from actual experience that many glue users are ignorant of the proper methods to be employed; and that many others are careless, or indifferent.

TABLE OF CONTENTS

 

CHAPTER I
IMPORTANCE OF THE INDUSTRY
Glue industry founded in America by Peter Cooper -increase in capital invested -increase in production – variety of uses -increase in requirements

CHAPTER II
THE MANUFACTURE OF GLUE
Sources from which glue is made – boiling the stock – drying – preparation in commercial form

CHAPTER III
TESTING AND GRADING GLUE
Grades established by Peter Cooper- the tests -viscosity or fluidity test- the jelly test- apparatus for making jelly test – the finger test-a simple, practical test for glue users- sampling bubbles – surface indications – color indications- alkaline or acid quality- breaking quality – foam — grease – keeping properties-odor-laboratory test.

CHAPTER IV
CORRECT METHODS IN THE GLUE ROOM
Much waste through faulty methods – importance of correct practice – soak glue in cold water before melting- test glue by water absorption – appliance for water absorption test- melting or dissolving glue – do not heat higher than 150°F. – apply heat indirectly – live steam ruins glue- use thermometer – heat glue slowly – cleaning the melting pot – importance of using copper, brass or aluminum utensils – guard against evaporation – melt only the amount required – importance of cleanliness – keeping the glue room warm – use by weight – storing – applying glue -securing workers’ co-operation.

CHAPTER V
MODERN GLUE ROOM EQUIPMENT
Modern appliances now available for all users only copper, brass or aluminum should come in contact with glue- the scientific glue heater-the automatic temperature controller – keep steam away from glue-glue spreaders – clamps and presses – distributing glue in large plants.

CHAPTER VI
WHICH GLUE TO USE
Accurate records important the best glue for wood joints – veneers- sizing – paper boxes – belting and other leather goods – bookbinding – emery purposes – how much to pay – waterproof glue-vegetable glue- quick setting glue-flexible glue.

 

 

GLUE is now so extensively used, and for so many different purposes, that it certainly deserves much more intelligent treatment at the hands of users than it has received heretofore.

Since 1837, in which year Peter Cooper, who may justly be regarded as the founder of the glue-making industry in the United States, produced the first American-made glue, the yearly output has steadily increased.
By 1880, the amount of capital invested in the making of glue had reached $4,000,000. In 1905, it was $10,000,000, and is now between $12,000,000 and $13,000,000.

The annual production has increased. in about the same ratio. In 1880, it was $4,000,000; at present it is about $15,000,000.

Glue is an important by-product of the great packing houses. Those in touch with the industry know how extensively glue enters into the manufacture of articles of everyday use. The general public hardly realizes that glue is used not only in making wood-joints and veneers, but in the production of paper, of silks, hats, carpets, rugs, and hundreds of other.

America now produces glue of excellent quality to meet practically all requirements. So great are the requirements that almost the entire amount of the American-made glue is absorbed by the home demand.

IN understanding of the sources from which glue is derived and of the processes of manufacture will be found of practical importance to the glue user. It will give many valuable side-lights on the proper methods of preparation and handling.
Glue is an organic substance of adhesive properties obtained from the hides, skins, bones and sinews of cattle, sheep, deer, horses, and other animals. Tails, snouts, ears, and the pith of the horn are also used. Some glue is produced from the heads, bones and sinews of fish.

The tendons and intestines of many animals, the swimming bladder of many varieties of fish; rabbit skins, or “coney,” from which the fur has been removed; old waste leather, such as gloves, butchers’ offal, or “country bone;” “junk” bones, and much other apparently worthless matter, all contribute to the raw material.

Being animal stock, the raw material of glue is subject to decomposition, and the scraps of hide are therefore carefully preserved, especially during The summer season.
The tanneries supply most of the hide stock, but only waste pieces reach the glue manufacturer, as leather is more valuable than glue, and , the larger portion is therefore reserved for the tanner’s use. Various names are used to describe the parts of hide that the tanner discards for the glue-maker’s use – the heavy trimmings are “pieces;” the hide pared off the hair or grain side, “skivings;” the parts scraped from the flesh side are “fleshings.”
At the packing houses the heads, feet, ribs, and other bony structures go direct to the glue-room. If bone is sweet and fresh it is known as “green,” or “packer” bone. The waste of button and knife factories is also used.

Bones are usually ground, and they are treated with a sulphuric acid bath to attack and separate the lime and gelatine of which the bone is composed. Bones, after being treated in this way, become pliable and soft, and the sulphuric acid is then removed by centrifugal force.
The acid must all be removed, as the glue will granulate if any remains.
Other parts of the stock are always carefully washed before boiling.
After the stock has been prepared, it is placed in a boiler with false bottom provided with an opening through which the liquid may be run off. The boiling of the stock is an operation that must be carefully conducted, as the application of a greater degree of heat, or for a longer time than is necessary, damages the glue.
The boiler is heated by direct firing. As the boiling proceeds, test quantities of the liquid are run off for examination, and when a sample is found on cooling to form a stiff jelly, it is ready to draw off.

The first boiling usually occupies about eight hours. When the liquid has been run off from this boiling, more water is added and the boiling is continued. This operation is repeated until the stock has yielded all of its gelatinous matter. As many as six or eight boilings may be made.
The liquid first run off – the “first boiling” -is always best, as the effect of repeated; or prolonged ‘application of heat is to weaken the glue tissue. The later boilings are also as a rule darker in color than the earlier ones.

DRYING
The glue solution from the boiling process is run into wooden troughs or “coolers,” about 6 feet long, 2 feet broad, and a foot deep, in which the solution sets in a firm jelly.
When set, a little water is run over the surface, the jelly is detached from the cooler, cut into uniform slices of the thickness desired, and placed on galvanized or linen nets to dry.

Drying may be done in the open air if weather conditions are favorable, or in a drying-room. The latter method is preferable. Conditions can be regulated to insure uniform drying.
Piles of the nets, or “stacks,” are loaded on trucks and taken into the drying- room, where they are exposed to the effect of warm air currents induced by blower or pressure fans, or exhaust or suction fans.
The drying is a source of concern to the manufacturer. It is extremely important to keep the temperature at just the right point, to protect the glue from dust and dirt, and to avoid the possibility of bacterial growth in the glue jelly, which is very susceptible to the development of harmful organisms.
The final form of the glue will be in sheets, strips or flakes, or ground. For commercial purposes it is put up in packages, bags and barrels.

 

 

HERE is as yet no uniformity of opinion among glue manufacturers and glue users as to how glue should be tested and graded. In a general way the manufacturer knows what kind of glue a certain stock will produce; but on account of variations that are sure to occur, it is necessary to subject each glue to certain tests, according to standards more or less definitely established.

The grades in general use are those originally employed by Peter Cooper, and are as follows:
A EXTRA
No.1
1x
1 1/4, 1 3/8, 1 1/2, 1 5/8, 1 3/4, 1 7/8

The only way to determine which is the best glue to use, is by trying out various grades in actual practice. The best glues for ordinary uses are well understood (see pages 79 to 85 for suggestions on this subject). Between two or more glues of any one type, actual experiment is the only safe guide. Most glue men will give you good advice; but above all, keep accurate records of results of the different grades used. When you have found the right glue, keep to it.

THE TESTS
Glue is graded on physical characteristics rather than on chemical composition. Various chemical tests have been proposed, but they are unimportant so far as practical working value is concerned.
The most important physical tests are those for viscosity, and jelly strength.

VISCOSITY OR FLUIDITY TEST
The test for viscosity, or fluidity, is based on the idea that the greater the tenacity of the glue, the greater will be its cohesiveness, and the less will be its flowing power. In other words, the higher will be its viscosity.
In testing for viscosity, water is used as a standard. A solution is made of the glue, and the rate of flow of the solution at a certain temperature is compared with the rate of flow of water under the same conditions.
Several devices are on the market under the name of “viscosimeter” for measuring the viscosity of glue.
While they vary in detail they are in principle a pipette from which the glue- solution flows at a given temperature. The time required for the glue to run out of the pipette as compared with the time consumed in the same operation by the same quantity of water gives the relative viscosity of the glue.
The viscosity test is not entirely accurate in itself, but taken in connection with the jelly test it forms a very satisfactory basis for grading.

THE JELLY TEST
The jelly test is based on the comparative resistance power of the varityus glue jellies. Several mechanical devices for determining jelly-strength have been perfected. One of these consists of a brass vessel which rests upon the glue jelly, and into which shot is poured; the weight of the cup and the contained shot upon having penetrated to a certain depth in the glue jelly, gives a figure which expresses the comparative strength of the jelly with the standard.

apparatus for testing jelly

APPARATUS FOR MAKING JELLY TEST
Another apparatus that has been found accurate and practical is the device illustrated on the next page. It consists of a pressure tube (A), over the mouth of which is stretched a thin rubber diaphragm (B). The tube connects to a rubber bulb (M) and to a pressure gauge, or manometer (E) with a scale (F). The pressure tube is filled with water to the point (C). The manometer tubes also contain water. A three-way stop-cock (D) connects the tubes either to the bulb (M), or to the air, depending on the position. Below the pressure tube is a brass table (G), on which is placed the glass containing the glue jelly to be tested.
When the glass is in position, the table is raised by means of a threaded wheel until the glue surface forces the water resting on the flexible diaphragm up to the fixed mark L. Then the stop-cock is turned to connect the pressure tube and gauge to the rubber bulb. By pressing the bulb the water is forced down in the pressure tube and so expands the .diaphragm into the jelly, the liquid in the gauge rising simultaneously. Pressure on the bulb is continued until the water reaches the mark N.
Thereupon the stop-cock is again turned, the water is held at the point N, and the pressure is indicated by the height of the liquid in the gauge. The degree of pressure is the measure of the consistency of the glue jelly.
The initial contact between the jelly and the rubber diaphragm is always the same, all jellies therefore having the same initial pressure. When the diaphragm is forced down into the jelly, the pressure required depends entirely upon the resistance that the jelly offers. The slightest difference in the consistencies of the various jellies will alter the pressure required, the differences being accurately recorded by the gauge upon the scale.
Advantages of this apparatus are that the relative value of the jelly compared with the standard is expressed in concrete figures; the method of operation is simple; and the instrument is so sensitive that it will record a change in reading between two samples of glue in which a difference of 1-40-th ounce of dry glue is used. Repeated tests may be made on the same jelly, as the surface is not broken. With a little practice a single glue may be tested in twenty seconds, or less.

THE FINGER TEST
One of the most satisfactory methods of determining jelly-strength – and the one perhaps in most general use, is the finger test.
In this tcst the various ‘glue jellies are arranged before the tester, who presses each with the tip of the finger, comparing it with the standard as to resistance- power. While this may seem to expose the final decision too greatly to the personal equation, as represented by the personality of the glue-tester, it is nevertheless true that an expert develops the most extraordinary precision, arriving at conclusions that are corroborated by the results of other tests and by the results in actual practice. The work of the glue-tester is analogous to that of the coffee-taster and the tea-taster, or experts in other lines, who through a highly developed and keenly discriminating sense of taste, or touch, or smell, determine with extreme nicety the physical characteristics of the substances that they are accustomed to test.

SOME SIMPLE, PRACTICAL TESTS FOR GLUE USERS
To perform the tests described requires a degree of experience and an equipment beyond the reach of the ordinary buyer and user of glue.
Certain tests may however be made that are of great value in determining important facts about the glue it is intended to buy and use.
These tests could not be used as a basis for grading glue scientifically, but they are exceedingly valuable in determining its purity and its adaptability to the work in hand.

SAMPLING
In the first place you should .carefully sample your glue with a view to testing.
Take several samples frfom various parts of the barrel. Flake glue is often made up of different varieties, and a single sample may not be at all representative. Ground glue, from its very nature, is easily adulterated. It should be examined in a good light, for evidence of foreign substances. Examine flake glue carefully also for uniformity of odor and general appearance. If glue has been adulterated while in original form it is practically impossible to determine the adulteration by external appearance. Subsequent adulteration may be detected.

BUBBLES
If you should notice white bubbles, in the shape ar round blots, on the surface of the glue, you have found evidence of decay. If there is any doubt in your mind you can complete the evidence by
moistening the glue. If it gives off a sour odor you have an additional indication of putrefaction. Such glue should be avoided.
Bubbles may appear within the glue – not on the surface – without being an indication of putrefaction. As a matter of fact, bubbles are practically always found in certain high-grade glues, though practically never in low-grade bone or hide glues. They are supposed to be due to the air which gets in when the glue is poured into the moulds.

When glue is originally dried on nets in very cool and dry weather, such bubbles are frequently found. Always beware of glue showing surface bubbles.

SURFACE INDICATIONS
Besides being free from bubbles or blots a good glue is smooth, though not necessarily glossy. Sometimes the very best glue will be of a dull color, and many inferior glues even have a very shiny surface. The surface should be uniform in color and in appearance.

COLOR INDICATIONS
These are not important, as a rule. The color of any particular lot of glue should be nearly uniform; otherwise it is subject to the suspicion of adulteration.
Bone glues are usually darker than hide glues, but some bone glues go through an artificial clarifying process which gives them the appearance of high- grade glues but really detracts from their strength. Very frequently oxide of zinc, is added to glue, the effect being to make it set quickly, as well as to give it; a light color. Some glues contain so much oxide of zinc that they are milk-white. Zinc oxide is not harmful except when added in very large quantities.

ALKALINE OR ACID QUALITY
The best glues are neutral as to acid and alkali. Glues with an excess of acid should be avoided, especially when used with oak or chestnut or other woods with strong acid qualities, as the acids in the glue may unite with those in the wood in such way as to have a destructive effect upon the glue. In such cases the glue will granulate after a time and the work will pull apart.
When a wood is being used that is strong in acid it is advisable to use a glue containing enough oxide of zinc to neutralize the acid in the wood. In making sizing for paper a glue containing either acid or alkali in excess should be avoided. It is also held by some authorities that acid in glue tends to bring about decay.
To test for alkali or acid, dissolve a small quantity of glue in water and dip a piece of litmus paper into the solution. Acid will turn the paper violet or red. Alkali will turn it blue. Litmus paper may be procured at any drug store.

BREAKING QUALITY
This is a simple test that affords an important indication of the quality of glue. Take a small piece bgtween the thumb and forefinger of each hand and bend it. A very thin piece of good glue will bend without breaking. When it does break, if the edges are splintery, great tensile strength is indicated. A clean fracture, on the other hand, indicates a brittle, low-grade glue, which has been subjected to heat so long as to destroy the tissue; or else it has been made from bone stock. High-grade glues never show glassy fractures, but bone glues do. In making this test, the air conditions of the room should be taken into account. If the glue has been kept in a dry room it will naturally break much more readily than if it has been in a moist atmosphere. This is especially important to bear in mind if comparative tests are being made.

FOAM
A simple test for foam is to beat a solution of glue with an ordinary eggbeater. Glue which shows foam, or in which foam does not quickly subside, probably contains impurities. Foam is especially frequent in alum-dried glues and in cheap bone glues.
Some authorities believe that foam is caused by overheating, due to scalding by contact with steam jacket, or by steam coming into direct contact with the glue, or by heating for too long a time, or it may be due to the fact that all the grease has not been eradicated.
Glue that foams at ordinary temperature should be avoided for good work.

GREASE
A moderate amount of grease may be a good thing when using with clay or with colors, but a large proportion of grease should be avoided when making glazed or coated papers, or in general use.

A glue at ordinary temperature which is not over-heated on which a scum rises has an excessive amount of grease. It shows that the glue has not been properly skimmed in manufacture.

KEEPING PROPERTIES
The keeping property of glue may be determined by letting the glue-jelly stand for several days exposed to the air, and noting any deterioration. It is customary to let the jelly stand at room temperature – but if the glue is to be kept under any special conditions the test should be made as nearly under these conditions as possible.

ODOR
Deterioration is always accompanied by a sour odor. Avoid using any glue that does not smell clean and sweet.

LABORATORY TESTS
Up-to-date practice in all the larger concerns using glue demands a laboratory for making tests. An expert is put in charge and the glue analyzed chemically as well as for its physical properties. This method cuts the guess-work down to a minimum. Manufacturers whose output would not permit the employment of an expert all the year round can have glue analyzed in laboratories maintained for such purposes. It means often a great saving of money in the end to learn the exact properties of the glue you propose to use, or that you may be actually using.
We may also repeat what we have already said about securing competent advice from manufacturers. The glue user who takes a responsible manufacturer or glue house into his confidence will secure valuable counsel.
It is to the glue maker’s and glue salesman’s interest to have you secure good results. They have a large experience to draw on, and when checked up by the results from actual practice in your glue room their advice in regard to the selection of glues is usually worth heeding.